个人简介:
袁康，博士，海南省D类高层次人才。本科毕业于中山大学，博士毕业于加拿大皇后大学。2018年到2023年先后在英国曼彻斯特大学和爱丁堡大学开展博士后研究工作。2024年加入海南大学。主要从事含主族元素的光电功能材料研究。近年来在Angew. Chem. Int. Ed., Chem. Soc. Rev., Chem. Sci.，ACS Catal., Org. Lett.等期刊发表论文三十余篇，其中第一作者和通讯作者论文15篇。部分论文被Nature Synthesis, ACS Editor’s Choice, Chemistry World, Chemistry Views, Chemical & Engneering News, Cheminform等高亮推荐。
科研项目:
1. 国家自然科学基金青年项目，主持。
2. 海南大学高层次人才启动基金，主持。
代表性研究成果：
1. X. Feng†, Z. Liu†, Q.-Y. Ni, B. Wang*, M. J. Ingleson, K. Yuan*, N-Directed Two-Fold Bromoboration of Diynes Enables Access to Brominated BN-Embedded PAHs, Org. Lett. 2024, 26, 10339–10344.
2. K. Yuan, A. K. Gupta, C. Si, M. Uzelac, E. Zysman-Colman*, M. J. Ingleson*, Brominated B1-Polycyclic Aromatic Hydrocarbons for the Synthesis of Deep-Red to Near-Infrared Delayed Fluorescence Emitters, Org. Lett. 2023, 25, 5880–5884.
Highlighted in Nat. Synth. 2023, 2, 807.
3. J. W. J. Hughes, D. J. Babula, F. Stowers-Veitch, K. Yuan, M. Uzelac, G. S. Nichol, M. J. Ingleson*, J. A. Garden*, NacNac-Zinc-Pyridonate Mediated ε-Caprolactone ROP, Dalton Trans. 2023, 52, 17767–17775.
Selected as Dalton Transactions Hot Article!
4. K. Yuan, M. J. Ingleson*, Haloboration of o-Alkynyl Phenols Generates Halogenated Bicyclic-Boronates, Angew. Chem. Int. Ed. 2023, 62, e202301463.*
5. M. E. Grundy†, L. Sotorrios†, M. K. Bisai, K. Yuan, S. A. Macgregor*, M. J. Ingleson*, Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C–H Borylation, ACS Catal. 2023, 13, 2286–2294.
6. S. A. Iqbal†, M. Uzelac†, I. Nawaz, Z. Wang, T. H. Jones, K. Yuan, C. R. P. Millet, G. S. Nichol, G. A. Chotana, M. J. Ingleson*, Amides as Modifiable Directing Groups in Electrophilic Borylation, Chem. Sci. 2023, 14, 3865–3872.
7. S. A. Iqbal†, C. R. P. Millet†, J. Pahl, K. Yuan, M. J. Ingleson*, Two Directing Groups Used for Metal Catalysed Meta‐C−H Functionalisation Only Effect Ortho Electrophilic C−H Borylation, Eur. J. Org. Chem. 2022, 44, e202200901.
8. C. R. P. Millet†, J. Pahl†, E. Noone, K. Yuan, G. S. Nichol, M. Uzelac, M. J. Ingleson*, Synthesis of Electrophiles Derived from Dimeric Aminoboranes and Assessing Their Utility in the Borylation of π Nucleophiles, Organometallics 2022, 41, 2638–2647.
9. N. Cironis, K. Yuan, S. P. Thomas, M. J. Ingleson*, XtalFluor‐E Enabled Regioselective Synthesis of Di‐Indole Sulfides by C3−H Sulfenylation of Indoles, Eur. J. Org. Chem. 2022, 10, e202101394.
10. J. Pahl†, E. Noone†, M. Uzelac, K. Yuan, M. J. Ingleson*, Borylation Directed Borylation of Indoles Using Pyrazabole Electrophiles: A One‐Pot Route to C7‐Borylated‐Indolines, Angew. Chem. Int. Ed. 2022, 61, e202206230. (VIP)
Highlighted in Angew. Chem. Int. Ed. 2022, 61, 40, e202210284.
11. S. Kirschner†, M. Peters, K. Yuan, M. Uzelac, M. J. Ingleson*, Developing Organoboranes as Phase Transfer Catalysts for Nucleophilic Fluorination Using CsF, Chem. Sci. 2022, 13, 2661–2668.*
Highlighted in Chemistry World: Study finds Goldilocks organoborane catalysts for fluorination.
12. K. Yuan†, D. Volland, S. Kirschner, M. Uzelac, G. S. Nichol, A. Nowak-Król*, M. J. Ingleson*, Enhanced N-Directed Electrophilic C–H Borylation Generates BN–[5]-and [6] Helicenes with Improved Photophysical Properties, Chem. Sci. 2022, 13, 1136–1145.
“Most popular 2022 supramolecular chemistry articles” in Chemical Science
“Most popular 2022 organic chemistry article” in Chemical Science
Part of the Chemical ScienceThemed Collection on "Emerging Frontiers in Aromaticity"
13. M. Uzelac, K. Yuan, G. S. Nichol, M. J. Ingleson*, Formation of a Hydride Containing Amido-Zincate Using Pinacolborane, Dalton Trans. 2021, 50, 14018–14026.
14. M. E. Grundy, K. Yuan, G. S. Nichol, M. J. Ingleson*, Zinc Catalysed Electrophilic C–H Borylation of Heteroarenes, Chem. Sci. 2021, 12, 8190–8198.
Highlighted in Chemistry News: Zinc-Catalyzed Borylation of Heteroarenes.
15. S. A. Iqbal, K. Yuan, J. Cid, J. Pahl, M. J. Ingleson*, Controlling Selectivity in N-Heterocycle Directed Borylation of Indoles, Org. Biomol. Chem. 2021, 19, 2949–2958.
16. S. Kirschner†, K. Yuan†, M. J. Ingleson*, Haloboration: Scope, Mechanism and Utility, New J. Chem. 2021, 45, 14855–14868.
17. M. Uzelac, K. Yuan, M. J. Ingleson*, A Comparison of Two Zinc Hydride Catalysts for Terminal Alkyne C–H Borylation/Hydroboration and the Formation of 1,1,1-Triborylalkanes by Tandem Catalysis Using Zn–H and B–H Compounds, Organometallics 2020, 39, 1332–1338.
18. S. A. Iqbal†, J. Pahl†, K. Yuan†, M. J. Ingleson*, Intramolecular (Directed) Electrophilic C–H Borylation, Chem. Soc. Rev. 2020, 49, 4564–4591.
19. K. Yuan, R. J. Kahan, C. Si, A. Williams, S. Kirschner, M. Uzelac, E. Zysman-Colman*, M. J. Ingleson*, The Synthesis of Brominated-Boron-Doped PAHs by Alkyne 1,1-Bromoboration: Mechanistic and Functionalisation Studies, Chem. Sci. 2020, 11, 3258–3267.
20. C. Zeng, K. Yuan, N. Wang, T. Peng, G. Wu, S. Wang*, The Opposite and Amplifying Effect of B←N Coordination on Photophysical Properties of Regioisomers with an Unsymmetrical Backbone, Chem. Sci. 2019, 10, 1724–1734.
21. S. A. Iqbal, J. Cid, R. J. Procter, M. Uzelac, K. Yuan, M. J. Ingleson*, Acyl‐Directed ortho‐Borylation of Anilines and C7 Borylation of Indoles Using Just BBr3, Angew. Chem. Int. Ed. 2019, 58, 15381–15385.
Highlighted in Chemical & Engneering News: Losing the metal to make organoboron bonds.
22. L. Dong, F. Saraci, K. Yuan, X. Wang, S. Wang*, Push-Pull Isomers of Indolizino [6,5,4,3-def] phenanthridine Decorated by a Triarylboron Moiety, Org. Biomol. Chem. 2019, 17, 6470–6477.
23. A. J. Warner, K. M. Enright, J. M. Cole, K. Yuan, J. S. McGough, M. J. Ingleson*, Borylative Cyclisation of Diynes Using BCl3 and Borocations, Org. Biomol. Chem. 2019, 17, 5520–5525.
24. S. Wang*, K. Yuan†, M.-F. Hu†, X. Wang, T. Peng, N. Wang, Q.-S. Li, Cleavage of Unstrained C−C Bonds in Acenes by Boron and Light: Transformation of Naphthalene into Benzoborepin, Angew. Chem. Int. Ed. 2018, 57, 1073–1077.
25. K. Yuan, X. Wang, S. Wang*, Cascade Dehydrogenative Hydroboration for the Synthesis of Azaborabenzofulvenes, Org. Lett. 2018, 20, 1617–1620.*
26. K. Yuan, G. Yousefalizadeh, F. Saraci, T. Peng, I. Kozin, K. G. Stamplecoskie*, S. Wang*, Impact of Ferrocene Substitution on the Electronic Properties of BODIPY Derivatives and Analogues, Inorg. Chem. 2018, 57, 14698–14704.
27. Y.-G. Shi, S. K. Mellerup, K. Yuan, G.-F. Hu, F. Sauriol, T. Peng, N. Wang, P. Chen, S. Wang*, Stabilizing Fleeting Intermediates of Stilbene Photocyclization with Amino-Borane Functionalization: The Rare Isolation of Persistent Dihydrophenanthrenes and Their [1,5] H-Shift Isomers, Chem. Sci. 2018, 9, 3844–3855.
28. K. Yuan, S. Wang*, trans-Aminoboration across Internal Alkynes Catalyzed by B(C6F5)3 for the Synthesis of Borylated Indoles, Org. Lett. 2017, 19, 1462–1465.
Selected as ACS Editor's Choice, one of the "Most Read Articles" in 2017.
29. K. Yuan, X. Wang, S. K. Mellerup, I. Kozin, S. Wang*, Spiro-BODIPYs with a Diaryl Chelate: Impact on Aggregation and Luminescence, J. Org. Chem. 2017, 82, 13481–13487.
30. A. L. Brazeau, K. Yuan, S.-B. Ko, I. Wyman, S. Wang*, Anion Sensing with a Blue Fluorescent Triarylboron Functionalized Bisbenzimidazole and Its Bisbenzimidazolium Salt, ACS Omega 2017, 2, 8625–8632.
31. S. K. Mellerup, K. Yuan, C. Nguyen, Z.-H. Lu, S. Wang*, Donor-Appended N, C-Chelate Organoboron Compounds: Influence of Donor Strength on Photochromic Behaviour, Chem. Eur. J. 2016, 22, 12464–12472.
32. K. Yuan, X. Wang, S. K. Mellerup, I. Wyman, G. Schatte, Z. Ding, S. Wang*, Triarylborane-Supported Polyferrocenyl Systems: Impact of the Linking Unit on Electronic and Electrochemical Properties, Organometallics 2016, 35, 3051–3059.
33. K. Yuan, N. Suzuki, S. K. Mellerup, X. Wang, S. Yamaguchi, S. Wang*, Pyridyl Directed Catalyst-Free trans-Hydroboration of Internal Alkynes, Org. Lett. 2016, 18, 720–723.
Highlighted in ChemInform.
34. D.-T. Yang, J. Radtke, S. K. Mellerup, K. Yuan, X. Wang, M. Wagner, S. Wang, One-Pot Synthesis of Brightly Fluorescent Mes2B-Functionalized Indolizine Derivatives via Cycloaddition Reactions, Org. Lett. 2015, 17, 2486–2489.
35. J.-L. Liu†, K. Yuan†, J.-D. Leng, L. Ungur, W. Wernsdorfer*, F.-S. Guo, L. F. Chibotaru*, M.-L. Tong*, A Six-Coordinate Ytterbium Complex Exhibiting Easy-Plane Anisotropy and Field-Induced Single-Ion Magnet Behaviour, Inorg. Chem. 2012, 51, 8538–8544.
